Dynamics of charge transfer excitons at PFP/PEN interfaces – Publication by B2 (Chatterjee) and A2 (Witte)

Members from projects B2 and A2 explored the dynamics of charge-transfer excitons at the internal interface in heterostructures of the organic donor-acceptor molecules pentacene and perfluoropentacene.

Reprinted with permission from A. Rinn et al, 2017, 9, 48, 42020–42028. Copyright 2017 American Chemical Society.

Organic photovoltaics is a vivid research field as it promises the fabrication of large scale and thin film devices on flexible supports. One of the key challenges is the separation of optically excited bound electron-hole pairs, so-called excitons. Of particular relevance are charge-transfer (CT) excitons at donor-acceptor interfaces with the electron in the acceptor and the hole in the donor molecule as they are prime candidates as intermediaries for charge separation. Studying these CT excitons in state-of-the-art devices is challenging as these consist of blends of molecular donors and acceptors in order to provide maximum internal interface area. The resulting, complex interface geometry structure hampers microscopic characterization of such CT-excitons and, in particular, denies a well-defined correlation of the electronic properties with the molecular packing at the interface. Hence, detailed studies on the underlying physical mechanism of charge-separation in organic photovoltaics rely on highly-ordered model heterojunctions.

In the present study, the researchers combine their expertise in the fabrication of such highly ordered crystalline molecular heterostructures with precise, time-resolved optical microspectroscopy to study the energetics and dynamics of CT-excitons at donor-acceptor interfaces for selected pentacene / perfluoropentacene heterostructures. Based on previous work, various molecular heterostructures with different molecular orientation are realized and further compared with the dynamics of blends, i.e., completely intermixed heterostructures, as well as the respective pure materials.

The spatial separation of electrons and holes in the CT-excitons leads to extended lifetimes compared to the pristine species. Intriguingly, the energetics reveal that the common description of such excitons based on a straight-forward orbital picture as a mere linear combination of the involved individual constituents is insufficient and a more intricate description of CT-excitons is needed. The present study provides the first experimental data systematically investigating such excitations in highly-ordered crystalline molecular heterostructures, which will enable further theoretical calculations on the involved electronic effects.

Publication

Andre Rinn, Tobias Breuer, Julia Wiegand, Michael Beck, Jens Hübner, Robin C. Döring, Michael Oestreich, Wolfram Heimbrodt, Gregor Witte, Sangam Chatterjee, Interfacial Molecular Packing Determines Exciton Dynamics in Molecular Heterostructures: the Case of Pentacene – Perfluoropentacene,
ACS Applied Materials & Interfaces, (2017) DOI: 10.1021/acsami.7b11118

Contact
Prof. Dr. Sangam Chatterjee
Institute of Experimental Physics I, Justus-Liebig-University Giessen
SFB 1083 Project B2 (Chatterjee)
https://www.uni-giessen.de/ipi
Tel. +49 (0)641 99-33100
Email: Sangam.Chatterjee@physik.uni-giessen.de

Prof. Dr. Gregor Witte
AG Molekulare Festkörperphysik, Philipps-Universität Marburg
SFB 1083 Project A2 (Witte)
https://www.uni-marburg.de/sfb1083/projects/A2
Tel. +49 (0)6421 28-21384
Email: Gregor.Witte@physik.uni-marburg.de

Alexander Lerch (B6) receives poster-prize at ESPMI9 in Singapore

Alexander Lerch, PhD-student in project B6 (Höfer/Wallauer) received an “ACS Nano Poster Prize” for his presentation at the international workshop EPSMI9 in Singapore.

We congratulate Alexander Lerch for being awarded a prize for his poster-presentation at the international workshop on “Electronic Structure and Processes at Molecular-Based Interfaces” (EPSMI9) in Singapore.

In his contribution, Alexander Lerch presented new insights into carrier dynamics at metal-molecule interfaces investigated by means of time resolved two-photon photoemission (2PPE). The experimental results obtained in model systems consisting of well-defined molecular layers deposited on single crystaline metal substrates highlight the capability of interface-related electronic states to mediate charge transfer.

Poster “Interface-specific mechanisms of charge transfer at metal-molecule contacts”
A. Lerch 1, F. Schiller 1,2, U. Höfer 1
1 Philipps-Universität-Marburg
2 Centro de Física de Materiales, San Sebastián, Spain
9th Electronic Structure and Processes at Molecular-Based Interfaces, 8-10. Nov. 2017, Nat. Univ. of Singapore

Klaus Stallberg (B6) is awarded dissertation-prize at TU Clausthal

Congratulations to Dr. Klaus Stallberg, who recently joined project B6 (Höfer/Wallauer) as a postdoc, for being awarded a dissertation-prize.

Congratulations to Dr. Klaus Stallberg, who recently joined project B6 as a postdoc, for being awarded a prize for his excellent dissertation at TU Clausthal on “Spectromicroscopic investigations of thin porphyrin layers and their influence on plasmonic excitations in silver structures by multi-photon-photoemission”.

In his thesis Klaus Stallberg investigated thin porphyrin films and plasmonic silver structures with multi-photon photoemission electronmicroscopy (nP-PEEM). Based on energy-resolved, time-resolved and laterally resolved nPPE experiments he porposed a model for the complex electronic excitation and relaxation processes in porphyrin films and was able to show how a thin porphyrin layer affects the dispersion of plasmons propagating on an extended silver island.

For these investigations he received one of three prizes (Förderpreis 1000 EUR) of the Friends of TU Clausthal (Verein von Freunden der Technischen Universität Clausthal e.V.).

Since July 2017 Klaus Stallberg explores the dynamics of charge transfer processes at interfaces of organic heterostructures by means of time-resolved two-photon photoemission in the framework of project B6 (Höfer/Wallauer).

Link to dissertation on TU Clausthal server.

TU Clausthal press release.