New Two-Dimensional Materials by Design – Publication by A11 (Heine) and B2 (Chatterjee)

Johanna Heine and Sangam Chatterjee break boundaries in two-dimensional materials’ design towards enhanced light-harvesting and emitting capabilities of hybrid perovskites

Low-dimensional organic−inorganic perovskites synergize the virtues of organic perovskites and inorganic two-dimensional (2D) materials featuring intriguing possibilities for next-generation optoelectronics: they offer tailorable building blocks for atomically thin, layered materials while providing the enhanced light-harvesting and emitting capabilities. However, the quest for new materials is limited by the generally-accepted paradigm that atomically thin materials require covalent in-plane bonding.

The groups of Dr. Heine (A11) and Prof. Chatterjee (B2) within the SFB 1083 lift this apparent paradigm and report single layers of the 1D organic–inorganic perovskite [C7H10N]3[BiCl5]Cl. Its unique 1D–2D interface structure enables single layers and the formation of self-trapped excitons, which show white-light emission. The thickness dependence of the emission energy may enable facile color tuning for next-generation lighting and display technologies.

This class of materials enables interface-controlled device integration of brightly luminescent 1D and 0D hybrid perovskites and offers a promising pathway for the non-covalent functionalization of classical 2D materials through heterostructures.

For further information, please see the press release by the Philipps-Universität Marburg (in German).

Publication

P. Klement, N. Dehnhardt, C.‐D. Dong, F. Dobener, S. Bayliff, J. Winkler, D.M. Hofmann, P.J. Klar, S. Schumacher, S. Chatterjee, J. Heine
Atomically Thin Sheets of Lead‐Free 1D Hybrid Perovskites Feature Tunable White‐Light Emission from Self‐Trapped Excitons
Adv. Mater. (2021) DOI:10.1002/adma.202100518

Contact

Dr. Johanna Heine
Philipps-Universität Marburg
SFB project A11
Tel.: 06421 28-22425
EMAIL

Prof. Dr. Sangam Chatterjee
Justus-Liebig-Universität Gießen
SFB project B2
Tel.: 0641 99-33100
EMAIL